12.3.047-98 
 .     ( ...   12.3.047-98 
 .     ( ...

12.3.047-98 => . ( )....

 
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,

 

 ->  .  ->  12.3.047-98 -> 
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()

 

( )

 

.1 . .

.2 , (% .), , , , , N,

= V, (.1)

- , % .

( = 100/([1 + 2,42(mC + 0,5mH - mO) + V];

V - , , :

, (.2)

- , /.

.3 , (% .),

= K, (.3)

.4 .1 .

 

.1

 

/

/

N2

34,9

CF2ClBr

449,0

2

43,6

F3r

573,0

2

55,9

CFCl3

142,0

2F3Cl3

218,0

CCl4

170,0

F6

150,0

CF4

90,0

CHF2Cl

110,0

34F31

208,0

2F2l2

170,0

38

216,0

2F4r2

830,0

C2F5C1

200,0

2F4Cl2

200,0

 

 

 

- 38 .

, 55,9 /, .1. (.2) V , - 103,85 /, , , 1400 :

(.1):

= 100/[1 + 2,42 (3 + 4) + 7,96] = 3,86 % (.);

= 3,86 7,96 = 30,7 % (.).

 

 

()

 

 

.1 , ( - ). , .

.2 . , , , .

.2.1 ( .1):

 

.1

 

,

,

,

,

2

3

4

5

6

1,0

2,0

2,5

3,0

3,6

7

8

9

15

4,0

5,0

6,3

10

 

.2.2 .2:

 

.2

 

,

,

,

,

15 15

18 18

10

15

25 25

35 35

20

25

 

.3 , 20 , 100 .

.4

d < 32,5 R T l / Su Cp p, (P.1)

R - ;

- . ;

l - , /();

Su - , /;

p - , /( );

- . .

.3:

 

.3

 

d,

d,

NH3 ( = 425 )

22,10

4O

2,70

C2H7N ( T = 375 )

2,84

34

2,05

24

3,08

3,04

22

0,85

24

1,60

36

2,45

512

2,49

-72

2,80

38

2,60

C6H6

2,66

36

2,38

410

2,49

CS2

0,75

462

5,34

C8H8

2,66

44

1,43

C7H8

3,78

23l

2,70

-

2,45

2

0,89

24O

5,59

C6H14

2,50

C6H12

2,66

716

3,08

510

4,63

40

2,74

26

4,63

512

2,49

26

2,97

4

3,50

24

1,75

 

.5 , , , (.1), , ().

 

 

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:

12.3.047-98

.

13.220

4854

3

1

2

3

4

5

6

7 ,

,

.1

.2 ,

.1

.3

Z = 0,5 F, (A.22)

, ()

.1 , ,

.2 , ,

B = (1 + S2) / (2S), (B.10)

= (2,722 + 4,102 + 1) / (2 4,1) = 3,08,

.1

.1

.1

.2

.3

.1

.1

.2

.2

.1

.2

( )

.1

.1

.2

.3

.1

.2

.3

.4

.5

.6 ,

.3

.4

.7 ,

.1

.1

.2

.2

.1

.2

.3

.4

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